Do you know if ntpdate is actually executed at boot? A log entry, perhaps (in, say, /var/log/dmesg might tell you what the problem is)?
A simple thing may be to check when ntpdate executes -- it has to wait for the network to be up (and would thus be one of the last things executed, well after inetd runs or the network manager, if you're using that, is up and running).
Hope this helps some.
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