Quote:
~/.config/pcmanfm/LXDE/pcmanfm.conf
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The "~/" means your home directory.
".config/" is a hidden directory. To see it choose "Show hidden files" in the View menu. Alternatively use a command line in a terminal and type "ls -al" in your home directory.
On my system the "pcmanfm/" doesn't exist. I suspect it's dependent on the desktop you're using and I am using MATE. Maybe you don't have it either?